Eur. Phys. J. B 24, 167-175 (2001)
https://doi.org/10.1007/s100510170004

Optical investigation of the quasi two-dimensional monophosphate tungsten bronzes K_xP₄W₈O₃₂ (x = 0 - 1.57)

¹ Physikalisches Institut, Universität Stuttgart, Pfaffenwaldring 57, 70550 Stuttgart, Germany
² ISMRA, Laboratoire CRISMAT (CNRS-UMR 6508) , 6 boulevard Maréchal Juin, 14050 Caen Cedex, France
³ Laboratoire d'Études des Propriétés Électroniques des Solides, CNRS, BP 166, 38042 Grenoble Cedex 9, France

Corresponding author: ^a dressel@pi1.physik.uni-stuttgart.de

Received: 27 April 2001
Revised: 21 September 2001
Published online: 15 November 2001

Abstract

The potassium doped monophosphate tungsten bronzes K_xP₄W₈O₃₂ are two-dimensional metals which show a metal-to-metal transition at a critical temperature which depends on the doping level. The metal-to-metal transition is accompanied by the formation of a commensurate charge density wave with wave vector (π/b,0) which is independent of the doping level. Undoped P₄W₈O₃₂, on the other hand, has two metal-to-metal transitions which are connected to the formation of incommensurate charge density waves. We measured the infrared reflectivity of the series K_xP₄W₈O₃₂ (x = 0 - 1.57) in the spectral range from 100 to 10 000 cm^-1 for room temperature and well below the critical temperature. Polarization-dependent infrared spectra find a two-dimensional behavior in the normal and the charge density wave state and show signatures of hybridization between one- and two-dimensional conduction bands. In undoped P₄W₈O₃₂ the essentials of the charge density wave state can be understood from the nesting vectors of the calculated Fermi surface and two gaps are observed in the infrared spectra. The gap sizes are a factor of about 2.5 bigger than the predictions from mean-field theory in the weak-coupling limit which suggests medium- or strong electron-phonon coupling. For potassium doped K_xP₄W₈O₃₂ one gap is observed in the charge density wave state. The energetics of the charge density formation may be dominated by the energy required for the lattice modulation.