Eur. Phys. J. B 3, 179-183 (1998)
https://doi.org/10.1007/s100510050300

Anharmonic behaviour of BaFCl using Raman scattering

Materials Science Division, Indira Gandhi Centre for Atomic Research, Kalpakkam-603 102, India

Corresponding author: ^a suka% msd@igcar.ernet.in

Received: 12 May 1997
Accepted: 25 July 1997
Published online: 15 May 1998

Abstract

Raman scattering from oriented single crystals of BaFCl was recorded at various temperatures from 20 to 1073 K for the first time. The Raman spectra, corrected for phonon population, were fitted to the sum of four Lorentzian peaks. The peak frequencies and full width at half maximum (FWHM) of the peaks were obtained from the fit. The FWHM is accounted for by cubic and quartic anharmonic processes. The quartic anharmonicity of the mode increases with the mode frequency. The quartic anharmonicity of the fluorine mode is exceptionally high. The peak frequencies decrease linearly with the increasing temperature. Fluorine mode frequencies decrease more than the internal mode frequencies do. The LO-TO splitting of the fluorine modes and that of the internal modes increases with temperature indicating the increase of the ionic bonding character. The results are discussed.