Eur. Phys. J. B 11, 609-614 (1999)
https://doi.org/10.1007/s100510051188

Morphology transition and slow dynamics in the collapse of amphiphilic monolayers at the air-water interface

¹ Nanoelectronics Laboratory, Graduate School of Engineering, Hokkaido University, Sapporo 060 - 0813, Japan
² Materials Division, Hokkaido National Industrial Research Institute, AIST, MITI, Sapporo 062 - 8517, Japan

Corresponding author: ^a hatta@nano.eng.hokudai.ac.jp

Received: 11 January 1999
Published online: 15 October 1999

Abstract

The morphology on collapsed monolayers at the air-water interface has been studied using phase contrast microscopy. It is found that the transition from randomly distributed to quasi-one dimensional crack pattern takes place, depending on the pH value of the subphase and the presence of specific divalent metal ions. In these macroscopic patterns, the former exhibits a surface roughening due to a monolayer buckling while the latter becomes more smooth and uniform. The occurrence of the former is instantaneous and the latter follows a slow dynamics, i.e., the crack propagation in monolayers occurs with a delay for crack nucleation. Thus the change of pattern indicates the existence of a dynamic transition. The transition is discussed with the scenario of a crack instability in brittle materials. The changes of viscous nature and of ion binding, and the compression direction probably operate for the observed behavior effectively.