https://doi.org/10.1007/s100510050981
Statics and kinetics at the nematic-isotropic interface in porous media
Faculty of Physics, University of Bucharest, P. O. Box MG-11,
Bucharest 76900, Romania
Corresponding author: a nita@scut.fisica.unibuc.ro
Received:
12
November
1998
Revised:
15
March
1999
Published online: 15 November 1999
We extend the random anisotropy nematic spin model to study nematic-isotropic transitions in porous media. A complete phase diagram is obtained. In the limit of relative low randomness the existence of a triple point is predicted. For relatively large randomness we have found a depression in temperature at the transition, together with a first order transition which ends at a tricritical point, beyond which the transition becomes continuous. We use this model to investigate the motion of the nematic-isotropic interface. We assume the system to be isothermal and initially quenched into the metastable régime of the isotropic phase. Using an appropriate form of the free energy density we obtain the domain wall solutions of the time-dependent Ginzburg-Landau equation. We find that including a random field leads to smaller velocity of the interface and to larger interface width.
PACS: 64.70.Md – Transitions in liquid crystals / 68.10.Jy – Kinetics (evaporation, adsorption, condensation, catalysis, etc.)
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 1999