https://doi.org/10.1007/s100510051022
Encapsulation of filaments of a self-assembling bicopper complex in polymer nanowires
Laboratoire de Dynamique
des Fluides Complexes,
Université Louis Pasteur (CNRS UMR 7506) ,
4 rue Blaise Pascal,
67070 Strasbourg Cedex, France
Corresponding author: a jm.guenet@univ-mulhouse.fr
Received:
20
January
1999
Revised:
14
May
1999
Published online: 15 December 1999
We report on the preparation conditions and the characterization by calorimetry and small-angle neutron scattering of a molecular composite material obtained via the heterogeneous nucleation of the fibrils of a thermoreversible gel. This physical process allows encapsulation of monomolecular filaments of a self-assembling bicopper complex into nanosized polymer fibrils. Due to the existence of 1-D arrangements of copper atoms, this material may possess unusual magnetic properties (spin ladders).
PACS: 81.05.-t – Specific materials: fabrication, treatment, testing and analysis / 82.70.Gg – Gels and sols / 61.41.+e – Polymers, elastomers, and plastics
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 1999