Eur. Phys. J. B 29, 441-455 (2002)
https://doi.org/10.1140/epjb/e2002-00325-4

Towards finite-dimensional gelation

Institut für Theoretische Physik, Universität Göttingen, Bunsenstr. 9, 37073 Göttingen, Germany

Corresponding author: ^a weigt@theorie.physik.uni-goettingen.de

Received: 24 April 2002
Published online: 14 October 2002

Abstract

We consider the gelation of particles which are permanently connected by random crosslinks, drawn from an ensemble of finite-dimensional continuum percolation. To average over the randomness, we apply the replica trick, and interpret the replicated and crosslink-averaged model as an effective molecular fluid. A Mayer-cluster expansion for moments of the local static density fluctuations is set up. The simplest non-trivial contribution to this series leads back to mean-field theory. The central quantity of mean-field theory is the distribution of localization lengths, which we compute for all connectivities. The highly crosslinked gel is characterized by a one-to-one correspondence of connectivity and localization length. Taking into account higher contributions in the Mayer-cluster expansion, systematic corrections to mean-field can be included. The sol-gel transition shifts to a higher number of crosslinks per particle, as more compact structures are favored. The critical behavior of the model remains unchanged as long as finite truncations of the cluster expansion are considered. To complete the picture, we also discuss various geometrical properties of the crosslink network, e.g. connectivity correlations, and relate the studied crosslink ensemble to a wider class of ensembles, including the Deam-Edwards distribution. 05.20.Jj Statistical mechanics of classical fluids