Eur. Phys. J. B 31, 95-102 (2003)
https://doi.org/10.1140/epjb/e2003-00013-y

Nonlinear dynamics of dimers on periodic substrates

Department of Theoretical Physics, University of Nijmegen, Toernooiveld 1, 6525 ED Nijmegen, The Netherlands

Corresponding author: ^a fusco@sci.kun.nl.

Received: 8 July 2002
Revised: 15 November 2002
Published online: 27 January 2003

Abstract

We study the dynamics of a dimer moving on a periodic one-dimensional substrate as a function of the initial kinetic energy at zero temperature. The aim is to describe, in a simplified picture, the microscopic dynamics of diatomic molecules on periodic surfaces, which is of importance for thin film formation and crystal growth. We find a complex behaviour, characterized by a variety of dynamical regimes, namely oscillatory, “quasi-diffusive” (chaotic) and drift motion. Parametrically resonant excitations of internal vibrations can be induced both by oscillatory and drift motion of the centre of mass. For weakly bound dimers a chaotic regime is found for a whole range of velocities between two non-chaotic phases at low and high kinetic energy. The chaotic features have been monitored by studying the Lyapunov exponents and the power spectra. Moreover, for a short-range interaction, the dimer can dissociate due to the parametric excitation of the internal motion.