https://doi.org/10.1140/epjb/e2004-00275-9
Optical evidence for the proximity to a spin-density-wave metallic state in Na0.7CoO2
1
Laboratorium für Festkörperphysik, ETH
Zürich, 8093 Zürich, Switzerland
2
Institut de physique de la matière complexe (IPMC), EPF Lausanne, 1015 Lausanne, Switzerland
3
Institute of Mineralogy and Geochemistry, University of Lausanne, 1015 Lausanne, Switzerland
Corresponding author: a degiorgi@solid.phys.ethz.ch
Received:
16
May
2004
Revised:
6
August
2004
Published online:
9
September
2004
We present the optical properties of Na0.7CoO2 single crystals, measured over a broad spectral range as a function of temperature (T).
The capability to cover the energy range from the far-infrared up to the ultraviolet allows us to perform reliable Kramers-Kronig transformation, in order to obtain the absorption spectrum (i.e., the complex optical conductivity). To the complex optical conductivity we apply the generalized Drude model, extracting the frequency dependence of the scattering rate (Γ) and effective mass (m*) of the itinerant charge carriers. We find that at low temperatures and for
. This suggests that Na0.7CoO2 is at the verge of a spin-density-wave metallic phase.
PACS: 78.20.-e – Optical properties of bulk materials and thin films / 74.70.Dd – Ternary, quaternary and multinary compounds (including Chevrel phases, borocarbides, etc.) / 75.30.Fv – Spin-density waves
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2004