https://doi.org/10.1140/epjb/e2006-00097-9
A definition of metastability for Markov processes with detailed balance
Centro de Ciencias Físicas, UNAM; Apartado postal 48-3, CP, 62251 Cuernavaca Morelos, Mexico
Corresponding author: a leyvraz@ce.fis.unam.mx
Received:
29
September
2005
Revised:
17
November
2005
Published online:
12
April
2006
A definition of metastable states applicable to arbitrary finite state Markov processes satisfying detailed balance is discussed. In particular, we identify a crucial condition that distinguishes genuine metastable states from other types of slowly decaying modes and which leads to properties similar to those postulated in the restricted ensemble approach [1]. The intuitive physical meaning of this condition is simply that the total equilibrium probability of finding the system in the metastable state is negligible. As a concrete application of our formalism we present preliminary results on a 2D kinetic Ising model.
PACS: 02.50.Ga – Markov processes / 05.20.Gg – Classical ensemble theory / 05.70.Ln – Nonequilibrium and irreversible thermodynamics
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2006