https://doi.org/10.1140/epjb/e2007-00041-7
Structural and magnetic properties of polymerized C60 with Fe
1
Department of Physics, Umeå University, 90187 Umeå, Sweden
2
Bayerisches Geoinstitut, Universität Bayreuth, 95440 Bayreuth, Germany
3
Division of Superconductivity and Magnetism, University of Leipzig, 04103 Leipzig, Germany
Corresponding author: a esquin@physik.uni-leipzig.de
Received:
29
November
2006
Revised:
16
January
2007
Published online:
9
February
2007
We provide evidence that high-pressure high-temperature (2.5 GPa and 1040 K) treatment of mixtures of iron with fullerene powders leads to the complete transformation of iron into iron carbide Fe3C. The comparison of the magnetic properties (Curie temperature and magnetic moment) of the here studied samples and those for the ferromagnetic polymer Rh-C60 indicates that the main ferromagnetic signal reported in those samples is due to Fe3C and not related to the ferromagnetism of carbon as originally interpreted. Taking into account the results obtained in this study the original paper on “Magnetic carbon" [Nature 413, 716 (2001)] was recently retracted.
PACS: 75.50.-y – Studies of specific magnetic materials / 75.50.Bb – Fe and its alloys / 72.80.Rj – Fullerenes and related materials
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2007