Eur. Phys. J. B 58, 115-121 (2007)
https://doi.org/10.1140/epjb/e2007-00218-0

Effect of Ta⁵⁺ substitution for Mn on the ground state of La_0.67Ca_0.33MnO₃

¹ XS & CGS, Materials Science Division, Indira Gandhi Centre For Atomic Research, Kalpakkam, 603102, Tamil Nadu, India
² Institute of Metallic Materials, IFW Dresden, Postfach 270116, Dresden, 01171, Germany

Corresponding author: ^a slaxmi73@gmail.com

Received: 12 April 2007
Revised: 28 June 2007
Published online: 10 August 2007

Abstract

We report the charge state modification effects at the Mn site on the ground state properties of colossal magnetoresistive manganites. Ta⁵⁺ substitution results in an appreciable increase in the lattice parameters and unit cell volume due to increased Mn³⁺ concentration. The ferromagnetic-metallic ground state modifies to a cluster glass insulator for . The reduction in the transition temperatures with increasing x is ∼39 K/at.%. Besides the modification of majority carrier concentration due to increased Mn³⁺ concentration and enhanced local structural effects, the local electrostatic potential of the substituent seems to contribute to the unusually strong reduction of the transition temperatures of the compounds. Thermo magnetic irreversibility just below Curie temperature (T_c), non-saturation of magnetization, two distinct magnetic transitions in ac susceptibility in an appropriate static field: close to T_c and other at low temperature (the spin freezing temperature (T_g)) and non-stationary dynamics with a characteristic maximum in the magnetic viscosity close to T_g confirm a cluster glass state for . These results find additional support from a linear low temperature magnetic specific heat of x = 0.10 with a characteristic broad maximum close to T_g.