Pressure-induced modifications of crystal and magnetic structure of oxygen deficient La0.7Sr0.3MnO3-d manganites
Frank Laboratory of Neutron Physics, JINR, 141980 Dubna, Russia
2 Joint Institute of Solids and Semiconductor Physics, NASB, P. Brovka str. 19, 220072 Minsk, Belarus
Corresponding author: a firstname.lastname@example.org
Published online: 14 September 2007
The crystal and magnetic structures of the oxygen deficient manganites La0.7Sr0.3MnO3-d (d = 0.15, 0.20) have been studied by means of powder neutron diffraction over the 0–5.2 GPa pressure and 10–290 K temperature ranges. La0.7Sr0.3MnO2.85 exhibits a coexistence of rhombohedral and tetragonal (I4/mcm) crystal structures and below Tg ~ 50 K a spin glass state is formed. La0.7Sr0.3MnO2.80 exhibits a tetragonal (I4/mcm) crystal structure. Below Tg ~ 50 K a phase separated magnetic state is formed, involving coexistence of C-type AFM domains with spin glass domains. In both compounds the crystal structure and magnetic states remain stable upon compression. The factors leading to the formation of different magnetic states in La0.7Sr0.3MnO3-d (d = 0.15, 0.20) and their specific high pressure behavior, contrasting with that of the stoichiometric A0.5Ba0.5MnO3 (A = Nd, Sm) compounds showing pressure-induced suppression of the spin glass state and the appearance of the FM state, are analysed.
PACS: 62.50.+p – High-pressure and shock wave effects in solids and liquids / 75.25.+z – Spin arrangements in magnetically ordered materials / 75.47.Lx – Manganites
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2007