https://doi.org/10.1140/epjb/e2011-10567-6
Physical properties, crystal and magnetic structure of layered Fe1.11Te1-xSex superconductors
1
Jülich Centre for Neutron Science JCNS and Peter Grünberg Institute PGI, JARA-FIT, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
2
Jülich Centre for Neutron Science, Forschungszentrum Jülich GmbH, Outstation at FRM II, Lichtenbergstraße 1, 85747 Garching, Germany
3
Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9, France
4
Solid State Physics Division, Bhabha Atomic Research
Centre, Trombay, 400 085 Mumbai, India
Corresponding author: a y.xiao@fz-juelich.de
Received:
22
July
2010
Revised:
29
April
2011
Published online:
6
July
2011
The physical and structural properties of Fe1.11Te and Fe1.11Te0.5Se0.5 have been investigated by means of X-ray and neutron diffraction as well as physical property measurements. For the Fe1.11Te compound, the structure distortion from a tetragonal to monoclinic phase takes place at 64 K accompanied with the onset of antiferromagnetic order upon cooling. The magnetic structure of the monoclinic phase was confirmed to be of antiferromagnetic configuration with a propagation vector k = (1/2, 0, 1/2) based on Rietveld refinement of neutron powder diffraction data. The structural/magnetic transitions are also clearly visible in magnetic, electronic and thermodynamic measurements. For superconducting Fe1.11Te0.5Se0.5 compound, the superconducting transition with Tc = 13.4 K is observed in the resistivity and ac susceptibility measurements. The upper critical field Hc2 is obtained by measuring the resistivity under different magnetic fields. The Kim's critical state model is adopted to analyze the temperature dependence of the ac susceptibility and the intergranular critical current density is calculated as a function of both field amplitude and temperature. Neutron diffraction results show that Fe1.11Te0.5Se0.5 crystalizes in tetragonal structure at 300 K as in the parent compound Fe1.11Te and no structural distortion is detected upon cooling to 2 K. However an anisotropic thermal expansion anomaly is observed around 100 K.
© EDP Sciences, Società Italiana di Fisica, Springer-Verlag, 2011