https://doi.org/10.1140/epjb/e2013-40905-5
Regular Article
Nonadiabatic Van der Pol oscillations in molecular transport
1
Mathematical Physics, Lund University,
22100
Lund,
Sweden
2 European Theoretical Spectroscopy Facility (ETSF),
3
Dipartimento di Fisica, Università di Roma Tor
Vergata, Via della Ricerca
Scientifica 1, 00133
Rome,
Italy
4
INFN, Laboratori Nazionali di Frascati,
Via E. Fermi 40, 00044
Frascati,
Italy
a
e-mail: cv@teorfys.lu.se
Received: 9 October 2013
Received in final form: 29 November 2013
Published online: 15 January 2014
The force exerted by the electrons on the nuclei of a current-carrying molecular junction can be manipulated to engineer nanoscale mechanical systems. In the adiabatic regime a peculiarity of these forces is negative friction, responsible for Van der Pol oscillations of the nuclear coordinates. In this work we study the robustness of the Van der Pol oscillations against high-frequency sources. For this purpose we go beyond the adiabatic approximation and perform full Ehrenfest dynamics simulations. The numerical scheme implements a mixed quantum-classical algorithm for open systems and is capable to deal with arbitrary time-dependent driving fields. We find that the Van der Pol oscillations are extremely stable. The nonadiabatic electron dynamics distorts the trajectory in the momentum-coordinate phase space but preserves the limit cycles in an average sense. We further show that high-frequency fields change both the oscillation amplitudes and the average nuclear positions. By switching the fields off at different times one obtains cycles of different amplitudes which attain the limit cycle only after considerably long times.
Key words: Mesoscopic and Nanoscale Systems
© EDP Sciences, Società Italiana di Fisica and Springer-Verlag, 2014