https://doi.org/10.1140/epjb/e2019-100145-1
Regular Article
Lowest frequency mode in Raman susceptibility: 2-propanol from ambient to supercritical condition
Yamagata University 1-4-12 Kojirakawa-machi,
Yamagata
990-8560, Japan
a e-mail: apj@cm.kj.yamagata-u.ac.jp
Received:
13
March
2019
Received in final form:
31
July
2019
Published online: 15 January 2020
We report the first observation of the low-frequency Raman spectra of 2-propanol from ambient to supercritical condition. Phenomenological analysis is applied to the reduced Raman spectra. The low-frequency component is decomposed into two components: the lowest mode represented by a MRT(multiple random telegraph) model and the 2nd mode represented by a modified Gaussian. Only the characteristic time of the lowest mode sensitively depends on density and decreases with increasing density. The integrated intensity of each mode is proportional to the density.
Key words: Solid State and Materials
© EDP Sciences / Società Italiana di Fisica / Springer-Verlag GmbH Germany, part of Springer Nature, 2020